উইকিপিডিয়া

আলোক আবর্তন

আলোক আবর্তন (Optical rotation বা পোলারাইজেশন রোটেশন বা সারকুলার বাইরেফ্রিজেন্স) হল নির্দিষ্ট পদার্থের মধ্য দিয়ে যাতায়াত করার সময় রৈখিক সমবর্তন আলোকের অপটিক্যাল অক্ষ সম্পর্কে সমবর্তন এর তলের অভিমুখীকরণের আবর্তন। সারকুলার বাইরেফ্রিজেন্স এবং সারকুলার ডিসক্রোইজম হ'ল অপটিকাল ক্রিয়াকলাপ এর প্রকাশ। অপটিকাল ক্রিয়াকলাপ কেবল কাইরাল পদার্থে ঘটে থাকে যাদের অণুবীক্ষণিক আয়নার প্রতিসাম্যের অভাব রয়েছে। অপটিকাল কার্যকলাপ তরল এ লক্ষ্য করা যায়। এর মধ্যে কাইরাল অণু যেমন শর্করা, হেলিকাল গৌণ কাঠামো সহ কিছু প্রোটিনযুক্ত অণু এবং কাইরাল তরল স্ফটিক এর গ্যাস বা দ্অরবণন্তর্ভুক্ত থাকতে পারে। এটি কাইরাল কঠিন যেমন নির্দিষ্ট স্ফটিকেও সংলগ্ন স্ফটিক তলের (যেমন কোয়ার্টজ) অথবা উপাদান এর মধ্যে লক্ষ্য করা যায়।

1. আলোক উৎস 2. অসমবর্তিত আলোক 3. সমবর্তক 4. সমবর্তিত আলোক 5. নমুনা টিউব যাতে জৈব অণু বর্তমান 6. ৩০° আলোক আবর্তন 7. সচল বিশ্লেষক 8. পর্যবেক্ষক

The rotation of the plane of polarization may be either clockwise, to the right (dextrorotary — d-rotary,represented by (+), or to the left (levorotary — l-rotary ,represented by (-) depending on which stereoisomer is present (or dominant). For instance, sucrose and camphor are d-rotary whereas cholesterol is l-rotary. For a given substance, the angle by which the polarization of light of a specified wavelength is rotated is proportional to the path length through the material and (for a solution) proportional to its concentration.

Optical activity is measured using a polarized source and polarimeter. This is a tool particularly used in the sugar industry to measure the sugar concentration of syrup, and generally in chemistry to measure the concentration or enantiomeric ratio of chiral molecules in solution. Modulation of a liquid crystal's optical activity, viewed between two sheet polarizers, is the principle of operation of liquid-crystal displays (used in most modern televisions and computer monitors).

ফ্যারাডে এফেক্টের সাথে তুলনা সম্পাদনা

Rotation of light's plane of polarization may also occur through the Faraday effect which involves a static magnetic field, however this is a distinct phenomenon that is not classified under "optical activity." Optical activity is reciprocal, i.e. it is the same for opposite directions of wave propagation through an optically active medium, for example clockwise polarization rotation from the point of view of an observer. In case of optically active isotropic media, the rotation is the same for any direction of wave propagation. In contrast, the Faraday effect is non-reciprocal, i.e opposite directions of wave propagation through a Faraday medium will result in clockwise and anti-clockwise polarization rotation from the point of view of an observer. Faraday rotation depends on the propagation direction relative to that of the applied magnetic field. All compounds can exhibit polarization rotation in the presence of an applied magnetic field, provided that (a component of) the magnetic field is oriented in the direction of light propagation. The Faraday effect is one of the first discoveries of the relationship between light and electromagnetic effects.

ইতিহাস সম্পাদনা

 
The two asymmetric crystal forms, dextrorotatory and levorotatory, of tartaric acid.
 
Sucrose solution concentration measuring experiment, demonstrating optical rotation.

The rotation of the orientation of linearly polarized light was first observed in 1811 in quartz by French physicist François Jean Dominique Arago.[১] In 1820, the English astronomer Sir John F.W. Herschel discovered that different individual quartz crystals, whose crystalline structures are mirror images of each other (see illustration), rotate linear polarization by equal amounts but in opposite directions.[২] Jean Baptiste Biot also observed the rotation of the axis of polarization in certain liquids[৩] and vapors of organic substances such as turpentine.[৪] Simple polarimeters have been used since this time to measure the concentrations of simple sugars, such as glucose, in solution. In fact one name for D-glucose (the biological isomer), is dextrose, referring to the fact that it causes linearly polarized light to rotate to the right or dexter side. In a similar manner, levulose, more commonly known as fructose, causes the plane of polarization to rotate to the left. Fructose is even more strongly levorotatory than glucose is dextrorotatory. Invert sugar syrup, commercially formed by the hydrolysis of sucrose syrup to a mixture of the component simple sugars, fructose, and glucose, gets its name from the fact that the conversion causes the direction of rotation to "invert" from right to left.

In 1849, Louis Pasteur resolved a problem concerning the nature of tartaric acid.[৫] A solution of this compound derived from living things (to be specific, wine lees) rotates the plane of polarization of light passing through it, but tartaric acid derived by chemical synthesis has no such effect, even though its reactions are identical and its elemental composition is the same. Pasteur noticed that the crystals come in two asymmetric forms that are mirror images of one another. Sorting the crystals by hand gave two forms of the compound: Solutions of one form rotate polarized light clockwise, while the other form rotate light counterclockwise. An equal mix of the two has no polarizing effect on light. Pasteur deduced that the molecule in question is asymmetric and could exist in two different forms that resemble one another as would left- and right-hand gloves, and that the organic form of the compound consists of purely the one type.

In 1874, Jacobus Henricus van 't Hoff[৬] and Joseph Achille Le Bel[৭] independently proposed that this phenomenon of optical activity in carbon compounds could be explained by assuming that the 4 saturated chemical bonds between carbon atoms and their neighbors are directed towards the corners of a regular tetrahedron. If the 4 neighbors are all different, then there are two possible orderings of the neighbors around the tetrahedron, which will be mirror images of each other. This led to a better understanding of the three-dimensional nature of molecules.

In 1945, Charles William Bunn[৮] predicted optical activity of achiral structures, if the wave's propgation direction and the achiral structure form an experimental arrangement that is different from its mirror image. Such optical activity due to extrinsic chirality was observed in the 1960s in liquid crystals.[৯][১০]

In 1950, Sergey Vavilov[১১] predicted optical activity that depends on the intensity of light and the effect of nonlinear optical activity was observed in 1979 in lithium iodate crystals.[১২]

Optical activity is normally observed for transmitted light, however, in 1988, M. P. Silverman discovered that polarization rotation can also occur for light reflected from chiral substances.[১৩] Shortly after, it was observed chiral media can also reflect left-handed and right-handed circularly polarized waves with different efficiencies.[১৪] These phenomena of specular circular birefringence and specular circular dichroism are jointly known as specular optical activity. Specular optical activity is very weak in natural materials.

In 1898 Jagadish Chandra Bose described the ability of twisted artificial structures to rotate the polarization of microwaves.[১৫] Since the early 21st century, the development of artificial materials has led to the prediction[১৬] and realization[১৭][১৮] of chiral metamaterials with optical activity exceeding that of natural media by orders of magnitude in the optical part of the spectrum. Extrinsic chirality associated with oblique illumination of metasurfaces lacking two-fold rotational symmetry has been observed to lead to large linear optical activity in transmission[১৯] and reflection[২০], as well as nonlinear optical acitvity exceeding that of lithium iodate by 30 million times.[২১]

তথ্যসূত্র সম্পাদনা

  1. ↑ Arago (1811) "Mémoire sur une modification remarquable qu'éprouvent les rayons lumineux dans leur passage à travers certains corps diaphanes et sur quelques autres nouveaux phénomènes d'optique" (Memoir on a remarkable modification that light rays experience during their passage through certain translucent substances and on some other new optical phenomena), Mémoires de la classe des sciences mathématiques et physiques de l'Institut Impérial de France, 1st part : 93–134.
  2. ↑ Herschel, J.F.W. (1820) "On the rotation impressed by plates of rock crystal on the planes of polarization of the rays of light, as connected with certain peculiarities in its crystallization," Transactions of the Cambridge Philosophical Society, 1 : 43–51.
  3. ↑ Biot, J. B. (1815) "Phenomene de polarisation successive, observés dans des fluides homogenes" (Phenomenon of successive polarization, observed in homogeneous fluids), Bulletin des Sciences, par la Société Philomatique de Paris, 190–192.
  4. ↑ Biot (1818 & 1819) "Extrait d'un mémoire sur les rotations que certaines substances impriment aux axes de polarisation des rayons lumineux" (Extract from a memoir on the [optical] rotations that certain substances impress on the axes of polarization of light rays), Annales de Chimie et de Physique, 2nd series, 9 : 372-389 ; 10 : 63-81 ; for Biot's experiments with turpentine vapor (vapeur d'essence de térébenthine), see pp. 72-81.
  5. ↑ Pasteur, L. (1850) "Recherches sur les propriétés spécifiques des deux acides qui composent l'acide racémique" (Researches on the specific properties of the two acids that compose the racemic acid), Annales de chimie et de physique, 3rd series, 28 : 56–99 ; see also appendix, pp. 99–117.
  6. ↑ van 't Hoff, J.H. (1874) "Sur les formules de structure dans l'espace" (On structural formulas in space), Archives Néerlandaises des Sciences Exactes et Naturelles, 9 : 445–454.
  7. ↑ Le Bel, J.-A. (1874) "Sur les relations qui existent entre les formules atomiques des corps organiques et le pouvoir rotatoire de leurs dissolutions" (On the relations that exist between the atomic formulas of organic substances and the rotatory power of their solutions), Bulletin de la Société Chimique de Paris, 22 : 337–347.
  8. ↑ Bunn, C. W. (১৯৪৫)। Chemical Crystallography। New York: Oxford University Press। পৃষ্ঠা 88। 
  9. ↑ R. Williams (১৯৬৮)। "Optical Rotatory Effect in the Nematic Liquid Phase of p-Azoxyanisole"। Physical Review Letters। 21 (6): 342। ডিওআই:10.1103/PhysRevLett.21.342। 
  10. ↑ R. Williams (১৯৬৯)। "Optical-rotary power and linear electro-optic effect in nematic liquid crystals of p-azoxyanisole"। Journal of Chemical Physics। 50 (3): 1324। ডিওআই:10.1063/1.1671194। 
  11. ↑ Vavilov, S. I. (১৯৫০)। Mikrostruktura Sveta (Microstructure of Light)। Moscow: USSR Academy of Sciences Publishing। 
  12. ↑ Akhmanov, S. A.; Zhdanov, B. V.; Zheludev, N. I.; Kovrigin, A. I.; Kuznetsov, V. I. (১৯৭৯)। "Nonlinear optical activity in crystals"। JETP Letters। 29: 264। 
  13. ↑ Silverman, M.; Ritchie, N.; Cushman, G.; Fisher, B. (১৯৮৮)। "Experimental configurations using optical phase modulation to measure chiral asymmetries in light specularly reflected from a naturally gyrotropic medium"। Journal of the Optical Society of America A। 5 (11): 1852। ডিওআই:10.1364/JOSAA.5.001852। 
  14. ↑ Silverman, M.; Badoz, J.; Briat, B. (১৯৯২)। "Chiral reflection from a naturally optically active medium"। Optics Letters। 17 (12): 886। ডিওআই:10.1364/OL.17.000886। পিএমআইডি 19794663। 
  15. ↑ Bose, Jagadis Chunder (১৮৯৮)। "On the Rotation of Plane of Polarisation of Electric Waves by a Twisted Structure"। Proceedings of the Royal Society। 63 (389–400): 146–152। এসটুসিআইডি 89292757। জেস্টোর 115973। ডিওআই:10.1098/rspl.1898.0019। 
  16. ↑ Svirko, Y.; Zheludev, N. I.; Osipov, M. (২০০১)। "Layered chiral metallic microstructures with inductive coupling"। Applied Physics Letters। 78 (4): 498। ডিওআই:10.1063/1.1342210। 
  17. ↑ Kuwata-Gonokami, M.; Saito, N.; Ino, Y.; Kauranen, M.; Jefimovs, K.; Vallius, T.; Turunen, J.; Svirko, Y. (২০০৫)। "Giant Optical Activity in Quasi-Two-Dimensional Planar Nanostructures"। Physical Review Letters। 95 (22): 227401। ডিওআই:10.1103/PhysRevLett.95.227401। পিএমআইডি 16384264। 
  18. ↑ Plum, E.; Fedotov, V. A.; Schwanecke, A. S.; Zheludev, N. I.; Chen, Y. (২০০৭)। "Giant optical gyrotropy due to electromagnetic coupling"। Applied Physics Letters। 90 (22): 223113। ডিওআই:10.1063/1.2745203। 
  19. ↑ Plum, E.; Fedotov, V. A.; Zheludev, N. I. (২০০৮)। "Optical activity in extrinsically chiral metamaterial" (পিডিএফ)। Applied Physics Letters। 93 (19): 191911। এসটুসিআইডি 117891131। ডিওআই:10.1063/1.3021082। 
  20. ↑ Plum, E.; Fedotov, V. A.; Zheludev, N. I. (২০১৬)। "Specular optical activity of achiral metasurfaces" (পিডিএফ)। Applied Physics Letters। 108 (14): 141905। ডিওআই:10.1063/1.4944775। 
  21. ↑ Ren, M.; Plum, E.; Xu, J.; Zheludev, N. I. (২০১২)। "Giant nonlinear optical activity in a plasmonic metamaterial"। Nature Communications। 3: 833। ডিওআই:10.1038/ncomms1805  । পিএমআইডি 22588295। 
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